By Y. Marcus, E. Yanir, A. S. Kertes
Equilibrium Constants of Liquid-Liquid Distribution Reactions, half III: Compound Forming Extractants, Solvating Solvents, and Inert Solvents specializes in the compilation of equilibrium constants of assorted compounds, equivalent to acids, ions, salts, and aqueous recommendations.
The manuscript provides tables that convey the distribution reactions of carboxylic and sulfonic acid extractants and their dimerization and different reactions within the natural section and extraction reactions of steel ions from aqueous suggestions. The booklet additionally states that the inorganic anions in those options are inappropriate, due to the fact they don't participate in the extraction response.
The ebook examines tables that illustrate the distribution of inorganic acids, salts, and complexes among aqueous strategies and solvents that experience oxygen donor atoms. Tables that express the distribution of inorganic acids, salts, and complexes among aqueous suggestions and inert solvents that don't have donor atoms and sometimes applied as inert diluents also are awarded.
The manuscript is a crucial reference for readers and researchers drawn to the equilibrium constants of compounds.
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Extra resources for Compound Forming Extractants, Solvating Solvents and Inert Solvents
02 CONDITIONS, 25 TEMP. D. , Anal. Chim. Acta, 9, 86 (1953). 2 LOG 53S H g ++ M + + A" + M + + A" + mA 2 = W +~K~~ 2m+l N Cs+ 1 O r,A" R E A C T Ligand: M METAL ION, 44 = ^2° IC1,A Ligand: G e +4 I',A" 1 MA, = MAT 4 4 Ligand: MA. = MAT 4 4 G e +4 A 2 + S = A 2'S Br ,A~ Ligand: A + S = AlT MA 3 + S = MA 3-S MA. 0 in CC1 4 chlorobenzene HA in chlorobenzene HA in chlorobenzene ORG. 63H 66H REF. 70 AQ. 52 TEMP. 57 LOG 45 TEMP. M. , J. Amer. Chem. , 4677 (1950). S. , Zhur. Priklad. , 25, 895 (1952).
Olszer, R. , J. Inorg. Nucl. , 28^, 1991 (1966). , J. Phys. , 2, 51 (1898). R E A C T I O N 98B M METAL ION, CONDITIONS, AQ. CONDITIONS, ORG. REF. 39 H g ++ Ligand Ag + Ligand: Ligand: + M = M 2S + M + + M + = MS MA 2 = MA^" H + + A~ = HA CI",A" MS + ++ ++ ++ = M 2S M+ + S = MS+ MS + M+ + S = MS+ MS + M+ + S = MS+ H + + A" = HA N03",A- + R E A C T I O N o,m,p-Xylene, S H 20 = H^O H 20 Extractant: M METAL ION. 68 m-xylene CONDITIONS, H 20 in H 2S 0 4 AQ. o-xylene • CONDITIONS, H 20 in H 2S 0 4 25 TEMP.
Inorg. Nucl. , 25, 1351 (1963). 5xl0"5 63S 25 AQ. 5 mg/£ Wichterle, I. , Coll. Czech. Chem. , 25, 2492 (1960). 71 ? 98 TEMP. Tribalat, S. , Anal. Chim. Acta, 8_, 22 (1953). D. , Anal. Chim. Acta, 9_, 86 (1953). V. , Acta Chim. Acad. Sci. , lj_, 317 (1957). , J. Phys. , 65^, 325 (1961). Siekierski, S. , J. Inorg. Nucl. , Z5, 1351 (1963). M. D. , Anal. , 39, 1180 (1968). 57S 61A 63S 64V 68M 666 (1964). , J. Chem. S o c , 2564 (1954). 20 57S in CC1. 02 25 4 REF. 6 54M = MA 0 . 2n+l Z ORG. 1 + C^H rN0 o 25% + CC1.