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Thau, F. and Shinnar, R. (1975). I&EC Pro cess Dev. & Des. 12. Palmor, Z . , Design of Controllers for Sampled Data Systems, AIChE meeting, Nov. 1977. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1978. ch001 1. SHINNAR Chemical Reactor Modeling 35 13. F. "Concepts i n Discrete Event Digital Stimula tion" J. Wiley, 1973. 14. R. (1962) Ind. Eng. Chem. Fund. 1, 200, 2, 183. 15. E. S. (1966). AIChE Journal 14, 77. 16. , Shinnar, R. Paper given at AIChE meeting, November 1977.
REFERENCES 1. W. Jr. (1975) Advances in Chemistry, No. 148, p. 98. 2. , Vol. 15 Control of Dynamic Systems, Advances in Theory and Application, Academic Press, 1978. 3. Lapidus, L. , editors; Chemical Reactor Theory, a Review, Prentice Hall, 1977. 4. Keane, Th. W. W. J r . ; Feedback on Reaction Engineering Techniques, Report to the National Science Foundation (1971). 5. B. , (1976), Chem. Eng. Science, 29, 1621. 6. J. (1967) I&EC, Vol. 59, p. 81. 7. , Chem. Eng. Sci. 20, 281 and 297. 8. A. and Watson, K.
Let us remember t h a t t h i s i s not always t r u e . In o b t a i n i n g 1L f o r a complex case the i n t e r a c t i o n between and and t h e exact d e f i n i t i o n o f the g o a l are always going to be important c o n s i d e r a t i o n s , i f we r e q u i r e a proper balance between the p o t e n t i a l v a l u e of i n c r e a s e d knowledge and the cost involved i n getting i t . There i s a b i g d i f f e r e n c e among complex lumped k i n e t i c models t h a t p r o v i d e s u f f i c i e n t i n f o r m a t i o n f o r one of the f o l lowing purposes: a) b) c) d) e) s a f e scaleup e f f i c i e n t c h a r a c t e r i z a t i o n of new c a t a l y s t s c h a r a c t e r i z a t i o n of feedstocks o p t i m i z a t i o n of design procedures e f f e c t of c a t a l y s t d e a c t i v a t i o n Witha f i n i t e e f f o r t we want to concentrate on improving the accuracy of our estimate f o r these p r o p e r t i e s of which a r e most r e l e v a n t t o our problem.