By Ernst Brose, Gunter Becker, Wolfgang Bouchain, Christiane Sprintz
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1-4) In terms of conversions the selectivity should be phrased as “the fraction of A converted into Q ” — not “the conversion of Q ” ! With complex processes like thermal cracking of a mixture of hydrocarbons to produce ethylene, use is often made of the “yield” of a component Q. ). Selectivities or yields depend upon the type of reactor in which the reaction is carried out. The selection and design of a reactor optimizing the selectivity for a desired product is a rewarding task for the engineer and will be illustrated in Chapter 10.
In the chlorination of benzene. The main feature is the presence of the common reactant B. 3-2) There is no simple solution for this set of differential equations as a function of time. 3-3) This is precisely what was obtained for the simpler consecutive first order case. The common reactant, B, has no effect on the selectivities but causes a different time behavior. 1-3) 22 CHAPTER 1: ELEMENTS OF REACTION KINETICS reflecting that the intermediate Q is transformed practically as soon as it is formed.
1-1) permits the calculation of the rate coefficient. This method for obtaining k is known as the "differential" method. 1-1), one set (CA ; t) suffices to calculate k when CA0 is known. In practice, it is necessary to check the value of k for a set of values of (CA ; t) or rather (rA ; t). 1-1), a number of values of n is chosen and the rate coefficient k is calculated for the sets (rA ; t). , independent of CA or t will be retained. This iterative procedure may be avoided by taking the logarithm of the rate equation.