By A. L., Wilson
This version covers the substantial advancements that have taken position (in the eleven years because the first version was once released) within the dimension of water caliber, with specific connection with equipment for estimating and controlling attainable error in analytical effects. summary: This version covers the significant advancements that have taken position (in the eleven years because the first variation was once released) within the size of water caliber, with specific connection with tools for estimating and controlling attainable blunders in analytical effects
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Extra info for Chemical Analysis Of Water : General Principles and Techniques
9. 3) and in evaluating the consequences of such quantification in terms of factors such as the required sampling frequency and accuracy of analytical results. Similarly, experts in computing systems may well be required when considering computerised datahandling systems. 3 DEFINING GRAMMES THE OBJECTIVES OF MEASUREMENT PRO- The following paragraphs essentially reproduce the text of the first edition; since they were written, the various suggestions have been adopted by a Working Group of the World Health Organization6 and by the Standing Committee of Analysts* of the United Kingdom's Department of the Environment.
As their numerical values are reduced, however, the analytical effort and cost needed to achieve them will usually increase and, at some point, become impracticably large. Care is required, therefore, to specify errors whose magnitudes are both tolerable and achievable. The values for c and p suggested above are equivalent to a maximum total error (95% confidence limits) of 20% at the higher concentration of a determinand. This may seem excessively large to many readers, but the author's experience, as mentioned above, is that this level of accuracy may be difficult to achieve - and perhaps even more difficult to show to have been achieved - for many determinands.
Yet again, detailed discussions between the user and the analyst on such points are invaluable. , but rather to a group of varied species with a common property of interest. Allen and Mancy23 used the term 'non-specific water-quality parameters' for such determinands, examples of which are: biochemical and chemical oxygen demands; electrical conductivity; taste; 16 Chemical Analysis of Water odour; filterability; etc. , taste, odour, appearance). For such determinands, two points are worth bearing in mind.